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‘Mechanism of Halide Exchange in Reactions of CpRu(PPh3)2Cl With Haloalkanes’
“Kinetic measurements of the reaction between CpRu(PPh3)2Cl (1a) and 1-bromobutane reveal a nearly first order dependence on the concentration of haloalkane and a negative entropy of activation, ΔS† < 0. The rate of halide exchange … is two orders of magnitude lower than the rate of phosphine dissociation. … DFT calculations are consistent with either oxidative addition or σ-bond metathesis as lower energy pathways than single electron transfer and formation of a radical pair.” Find the paper and the full list of authors in the New Journal of Chemistry.