All Work
Title
Topic
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Combating bias in early childhood educators
Urbani, et al., argue that pre-school and serve as an on-ramp to two results: inclusive education on the one hand, and the “school-to-prison nexus” on the other. To support the latter and mitigate the former, they demonstrate how developing a “critical consciousness, particularly around the intersections of race and disability,” in early childhood educators, and early classrooms, is crucial to making pre-school a welcome, inclusive environment for all students. See the full list of authors and read their research paper, “Building the on-ramp to inclusion: Developing critical consciousness in future early childhood educators,” at Research Connections.
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‘Mechanism of Halide Exchange in Reactions of CpRu(PPh3)2Cl With Haloalkanes’
“Kinetic measurements of the reaction between CpRu(PPh3)2Cl (1a) and 1-bromobutane reveal a nearly first order dependence on the concentration of haloalkane and a negative entropy of activation, ΔS† < 0. The rate of halide exchange … is two orders of magnitude lower than the rate of phosphine dissociation. … DFT calculations are consistent with either oxidative addition or σ-bond metathesis as lower energy pathways than single electron transfer and formation of a radical pair.” Find the paper and the full list of authors in the New Journal of Chemistry.